Re-cyclic photophysics in perovskite Cs<sub>4</sub>PbBr<sub>6</sub>

نویسندگان

چکیده

Most photophysical studies in the halide perovskite have focused on characteristics of surface. However, photons generated at surface would be absorbed by same material (re-absorption), and photophysics re-absorbed are rarely studied. Herein, we present our recent observation re-emission (photoluminescence after re-absorption, IR) Cs4PbBr6, which is temporally slower than surface-emission (IS). We performed a characterization power dependence experiment, lifetime measurement to reveal emitting properties Cs4PbBr6. characterized first (re-emission IFR) The analysis IFR revealed that energy intervals between IS final (IR) close integer multiples. Therefore, suggested least number repeated re-absorptions required for generating IR three.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Insights into cationic ordering in Re-based double perovskite oxides

Cationic ordering in Sr2FeReO6 (SFRO) and Sr2CrReO6 (SCRO) is investigated using magnetic property measurement, atomic-scale imaging, and first-principles calculations. We find that the nature of cationic ordering strongly depends on the host oxides, although they have the same crystal symmetry and chemical formula. Firstly, adding Re is effective to enhance the cationic ordering in SFRO, but m...

متن کامل

CH3NH3PbI3 perovskite single crystals: surface photophysics and their interaction with the environment.

Here we identify structural inhomogeneity on a micrometer scale across the surface of a CH3NH3PbI3 perovskite single crystal. At the crystal edge a local distortion of the crystal lattice is responsible for a widening of the optical bandgap and faster photo-carrier recombination. These effects are inherently present at the edge of the crystal, and further enhanced upon water intercalation, as a...

متن کامل

Synthesis, characterization, and photophysics of oxadiazole- and diphenylaniline-substituted Re(I) and Cu(I) complexes.

Transition-metal complexes of the types [Re(CO)(3)Cl(NN)], [Re(CO)(3)py(NN)](+), and [Cu(PPh(3))(2)(NN)](+), where NN = 4,4'-bis(5-phenyl-1,3,4-oxadiazol-2-yl)-2,2'-bipyridine (OX) and 4,4'-bis(N,N-diphenyl-4-[ethen-1-yl]-aniline)-2,2'-bipyridine (DPA), have been synthesized and characterized. Crystal structures for [Re(CO)(3)Cl(DPA)] and [Cu(PPh(3))(2)(OX)]BF(4) are presented. The crystal stru...

متن کامل

The photophysics of fac-[Re(CO)3(NN)(bpa)](+) complexes: a theoretical/experimental study.

The influence of the polypyridyl ligand on the photophysics of fac-[Re(CO)3(NN)(bpa)](+), bpa = 1,2-bis-(4-pyridyl)ethane and NN = 1,10-phenanthroline (phen), pyrazino[2,3-f][1,10]-phenanthroline (dpq), and dipyrido[3,2-a:2'3'-c]phenazine (dppz) has been investigated by steady state and time-resolved emission spectroscopy combined with theoretical calculations using time-dependent density funct...

متن کامل

Synthesis, structure, photophysics and electrochemiluminescence of Re(I) tricarbonyl complexes with cationic 2,2-bipyridyl ligands.

Two water soluble Re(I) tricarbonyl diimine complexes containing cationic 2,2'-bipyridyl ligands [Re(L1)(CO)(3)(AN)](2+) (1) and [Re(L2)(CO)(3)(AN)](3+) (2) (L1 and L2: a cationic 2,2'-bipyridyl ligand, AN: acetonitrile) were synthesized and characterized. Their photophysical, electrochemical and electrochemiluminescent properties were investigated. The crystal structures of the two complexes h...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Applied Physics Letters

سال: 2021

ISSN: ['1520-8842', '0003-6951', '1077-3118']

DOI: https://doi.org/10.1063/5.0053583